http://www.shroudstory.com/faq/index.htm
Madder root dyes (Alizarin and Purpurin), gum, a hydrous oxide mordant, cotton fibers and significant levels of vanillin (4-hydroxy-3-methoxybenzaldehyde) have been found in the carbon 14 sample area and not anywhere else on the Shroud. The startling conclusion is that what was radiocarbon dated was chemically unlike the rest of the cloth. Thus it was an invalid sample.
Chemical and Texitile composition of the tested area
http://www.shroudstory.com/faq/turin-shroud-faq-05.htm
The non-image cloth typically shows weak fluorescence (upper right). When image appears on the cloth, it quenches the fluorescence and gives it a brown color (see "Hands" below). The small, triangular, white area is where the Raes sample was cut in 1973. The radiocarbon sample was cut upward from there about 1 cm to the right of the seam and about 7 cm long. The area where the radiocarbon sample was taken is relatively dark, a fact that is not the result of dirt, image color, or scorching. The cloth is much less fluorescent in that area, brightening into more typical fluorescence to the right. The photograph proves that the radiocarbon area has a different chemical composition than the main part of the cloth. This was obviously not considered before the sample was cut.
Raes and radiocarbon yarn show colored encrustations on their surfaces. Some sections of medulla contain some of the material, showing that it had been able to flow by capillary attraction as a liquid. The encrustation is not removed by nonpolar solvents, but it swells and dissolves in water.

This photomicrograph shows several fibers from the center of the radiocarbon sample in water. The gum is swelling and slowly detaching from the fibers. Many red alizarin/mordant lakes can be seen, and yellow dye is in solution in the gum. Several cotton fibers are visible, a situation unique to the radiocarbon samples.
There was absolutely no encrustation on either the Holland cloth or fibers from the main part of the Shroud.
Al Adler had found large amounts of aluminum in yarn segments from the radiocarbon sample, up to 2%, by energy-dispersive x-ray analysis. I found that the radiocarbon sample was uniquely coated with a plant gum (probably gum Arabic), a hydrous aluminum oxide mordant (the aluminum found by Adler), and Madder root dye (alizarin and purpurin). Nothing similar exists on any other part of the Shroud. The photomicrograph shows several fibers from the center of the radiocarbon sample in water. The gum is swelling and slowly detaching from the fibers. Many red alizarin/mordant lakes can be seen, and yellow dye is in solution in the gum. Several cotton fibers are visible, a situation unique to the Raes and radiocarbon samples.
The radiocarbon sampling area had been dyed to match the old part of the cloth. The sample chosen for dating was totally invalid for determining the true age of the Shroud.
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Most people associate "Vanillin" with the dating process of the shroud. But very few consider how it is used to determine the tempurature of the image making process.
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The kinetics of vanillin elimination from lignin that determine a low temperature image-formation processhttp://www.shroudstory.com/faq/turin-shroud-faq-08.htm
Glucose decomposes by a multi-step process. As with all of the other saccharides, the first is a dehydration/condensation reaction. The condensation processes yield carbon-carbon double bonds, which ultimately lead to color formation. Bruce Waymack of Philip Morris measured the kinetics of the first reaction as E = 23.9 kcal/mole and Z = 1.26 X 107 s-1. The low-molecular-weight polysaccharides are much less stable than cellulose.
I measured the kinetics of vanillin elimination from lignin as E = 23.6 kcal/mol and Z = 3.7 X 1011 s-1. It is much less stable than crystalline cellulose.
Results of kinetics studies support a lowÂtemperature image-formation process. The temperature was not high enough to change cellulose within the time available for image formation, and no char was produced.
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These following two discussions on Vanillin and Lignin are the one skeptics over react to as a dating process to determine the Shroud's Date. But we can discuss them openly here without concern of debate ramifications of the discussion. Let's do it!

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Are there any other ways than radiocarbon to date the Shroud of Turin?
http://www.shroudstory.com/faq/turin-shroud-faq-13.htm
Some compounds like lignin change composition with time. The lignin in the Shroud does not give the normal microchemical test for vanillin, indicating that it is quite old. Measurements of the chemical rate for loss of vanillin estimates an age for the Shroud of more than 1300 years, depending on storage conditions.
Lignin
http://www.shroudstory.com/faq/turin-shroud-faq-14.htm
Lignin is a structural polymer that is found in all plants, including flax. Linen is bleached in an effort to remove as much lignin as possible, but some lignin always remains in linen. Lignin slowly ages with the loss of vanillin (4-hydroxy-2-methoxybenzaldehyde). A very sensitive microchemical test exists for the detection of traces of vanillin. It is easy to detect vanillin in modern lignin, it is harder to find in Medieval linen, and no test can be obtained from the few Shroud fibers that are still available for study. The lignin in samples from the Dead Sea scrolls (ca. AD 70) does not give the vanillin test. This observation would suggest that the linen of the Shroud is very old, casting doubt on the accuracy of the 1988 date. Observations on the lignin could be confirmed with samples from the "restoration"; however, such samples are jealously guarded in Turin.
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Let's have some productive sharing my friends.
Knowledge is worth the effort. Wisdom is worth the experience. Resolution of the tensions of competing ideas leads to learning and growth. - joer 5/3/2009
